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P&G Professional FAIRY Non Bio
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Date of issue: 27/01/2015 SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product
identifier
: P&G Professional FAIRY Non Bio Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Main use category : Professional use Function or use category : Washing and cleaning products (including solvent based products) 1.2.2. Uses
No additional information available
1.3.
Details of the supplier of the safety data sheet
Procter & Gamble UK Brooklands, Weybridge, Surrey, KT13 0XP, UK
Tel: 01932 896000 Fax: 01932 896200
Professional: [email protected]
1.4. Emergency
telephone
Emergency number : (UK) Emergency Tel: 0800 328 8304(IRL) Emergency Tel: 1800 509 497 SECTION 2: Hazards identification
Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Eye Irrit. 2 H319
Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Xi; R36
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2. Label
elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP)
Signal word (CLP) Hazard statements (CLP) : H319 - Causes serious eye irritation Precautionary statements (CLP) : P101 - If medical advice is needed, have product container or label at hand P102 - Keep out of reach of children P301+P312 - IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention
2.3. Other
Other hazards not contributing to the : No presence of PBT and vPvB ingredients. SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
P&G Professional FAIRY Non Bio
Safety Data Sheet
according to Regulation (EC) No. 453/2010

3.2. Mixture
Product identifier
Classification according to
Classification according to
Directive 67/548/EEC
Regulation (EC) No.
1272/2008 [CLP]
Sodium Carbonate (CAS No) 497-19-8 Eye Irrit. 2, H319 (EC no) 207-838-8 (EC index no) 011-005-00-2 (REACH-no) 01-2119485498-19 Sodium Carbonate Peroxide (CAS No) 15630-89-4 Ox. Sol. 3, H272 (EC no) 239-707-6 Acute Tox. 4 (Oral), H302 (REACH-no) 01-2119457268-30 Eye Dam. 1, H318 Sodium C10-13 Alkyl Benzenesulfonate (CAS No) 68411-30-3 Acute Tox. 4 (Oral), H302 (EC no) 270-115-0 Skin Irrit. 2, H315 (REACH-no) 01-2119489428-22 Eye Dam. 1, H318 Aquatic Chronic 3, H412 (CAS No) 1344-09-8 Skin Irrit. 2, H315 (EC no) 215-687-4 Eye Dam. 1, H318 Sodium C12-15 Pareth Sulfate (CAS No) 91648-56-5 Skin Irrit. 2, H315 (EC no) 293-918-8 Eye Dam. 1, H318 Aquatic Chronic 3, H412 (CAS No) 77-92-9 Eye Irrit. 2, H319 (EC no) 201-069-1 (CAS No) 68951-67-7 Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 Full text of R- and H-phrases: see section 16 SECTION 4: First aid measures
Description of first aid measures
First-aid measures after inhalation : IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact : IF ON SKIN: Wash with plenty of soap and water. Remove/Take off immediately all contaminated clothing. If skin irritation occurs: Get immediate medical advice/attention. Discontinue use of product. First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. First-aid measures after ingestion : IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : Coughing. sneezing. Symptoms/injuries after skin contact : Redness. Swelling. dryness. Itching. Symptoms/injuries after eye contact : Severe pain. Redness. Swelling. Blurred vision. Symptoms/injuries after ingestion : Oral mucosal or gastro-intestinal irritation. Nausea. Vomiting. Excessive secretion. Diarrhoea. Indication of any immediate medical attention and special treatment needed
Refer to section 4.1. SECTION 5: Firefighting measures

5.1. Extinguishing
Suitable extinguishing media : Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Special hazards arising from the substance or mixture
: No fire hazard. Non combustible. Explosion hazard : Product is not explosive. : No dangerous reactions known. Advice for firefighters
Firefighting instructions : No specific firefighting instructions required. Protection during firefighting : In case of inadequate ventilation wear respiratory protection. SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
6.1.1. For
personnel
Protective equipment : Wear suitable gloves and eye/face protection. P&G Professional FAIRY Non Bio
Safety Data Sheet
according to Regulation (EC) No. 453/2010

6.1.2. For
emergency
responders
Protective equipment : Wear suitable gloves and eye/face protection.
6.2. Environmental
precautions
Consumer products ending up down the drain after use. Prevent soil and water pollution. Prevent spreading in sewers.
6.3.
Methods and material for containment and cleaning up
: Scoop solid spill into closing containers. Methods for cleaning up : Small quantities of solid spill: wash down with water. Large spills: scoop solid spill into closing containers. This material and its container must be disposed of in a safe way, and as per local legislation. Other information : Avoid contact with skin, eyes and clothing. Reference to other sections
Refer to Sections 8 and 13. SECTION 7: Handling and storage

7.1. Precautions
handling
Precautions for safe handling : Avoid contact with eyes. Use personal protective equipment as required. Avoid raising dust. Do not eat, drink or smoke when using this product. Do not handle until all safety precautions have been read and understood. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in original container. Refer to section 10. Incompatible products : Refer to section 10. Incompatible materials : Not applicable. Prohibitions on mixed storage : Not applicable. : Store in a cool area. Store in a dry area. Store away from heat.
7.3. Specific
Cleaning/washing agents and additives. SECTION 8: Exposure controls/personal protection

8.1. Control
parameters
National limit values
No additional information available Monitoring procedures: DNELS, PNECS, OEL
Citric Acid (77-92-9)
PNEC (Water)
PNEC aqua (freshwater)
PNEC aqua (marine water) PNEC (Sediment) PNEC sediment (freshwater) PNEC sediment (marine water) PNEC (Soil) PNEC soil PNEC (STP) PNEC sewage treatment plant Sodium Carbonate (497-19-8)
DNEL/DMEL (Workers)
Long-term - local effects, inhalation
DNEL/DMEL (General population) Acute - local effects, inhalation Sodium C10-13 Alkyl Benzenesulfonate (68411-30-3)
DNEL/DMEL (Workers)
Long-term - systemic effects, dermal
170 mg/kg bodyweight/day Long-term - systemic effects, inhalation Long-term - local effects, inhalation DNEL/DMEL (General population) Long-term - systemic effects,oral 0.85 mg/kg bodyweight/day Long-term - systemic effects, inhalation P&G Professional FAIRY Non Bio
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Sodium C10-13 Alkyl Benzenesulfonate (68411-30-3)
Long-term - systemic effects, dermal
85 mg/kg bodyweight/day Long-term - local effects, inhalation PNEC (Water) PNEC aqua (freshwater) PNEC aqua (marine water) PNEC aqua (intermittent, freshwater) PNEC (Sediment) PNEC sediment (freshwater) PNEC sediment (marine water) PNEC (Soil) PNEC soil PNEC (STP) PNEC sewage treatment plant Sodium Silicate (1344-09-8)
DNEL/DMEL (Workers)
Long-term - systemic effects, dermal
1.59 mg/kg bodyweight/day Long-term - systemic effects, inhalation DNEL/DMEL (General population) Long-term - systemic effects,oral 0.8 mg/kg bodyweight/day Long-term - systemic effects, inhalation Long-term - systemic effects, dermal 0.8 mg/kg bodyweight/day PNEC (Water) PNEC aqua (freshwater) PNEC aqua (marine water) PNEC aqua (intermittent, freshwater) PNEC (STP) PNEC sewage treatment plant Sodium Carbonate Peroxide (15630-89-4)
DNEL/DMEL (Workers)
Acute - local effects, dermal
Long-term - local effects, dermal 12.8 mg/kg bodyweight/day Long-term - local effects, inhalation DNEL/DMEL (General population) Acute - local effects, dermal Long-term - local effects, dermal PNEC (Water) PNEC aqua (freshwater) PNEC aqua (marine water) PNEC aqua (intermittent, freshwater) PNEC (STP) PNEC sewage treatment plant
8.2. Exposure
controls
Appropriate engineering controls Personal protective equipment Protective personal equipment only required in case of professional use or for large packs (not for household packs). For consumer use please follow recommendation as indicated on the label of the product. Wear eye/face protection. Skin and body protection Respiratory protection Environmental exposure controls P&G Professional FAIRY Non Bio
Safety Data Sheet
according to Regulation (EC) No. 453/2010

SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Property
Test method/Notes
Appearance Solid. White with coloured speckles. No data available No data available No data available No data available No data available Relative evaporation rate (butylacetate=1) No data available Flammability (solid, gas) No data available Explosive limits No data available No data available Relative density No data available Solubility Soluble No data available Auto-ignition temperature No data available Decomposition temperature No data available No data available Explosive properties No additional information available Oxidising properties No additional information available
9.2. Other
information
No additional information available SECTION 10: Stability and reactivity

10.1. Reactivity
No dangerous reactions known.
10.2. Chemical
stability
Stable under normal conditions.
10.3. Possibility
hazardous
reactions
Refer to section 10.1 on Reactivity.
10.4.
Conditions to avoid
Not required for normal conditions of use.
10.5. Incompatible
materials
Not applicable.
10.6. Hazardous
products
None under normal use. SECTION 11: Toxicological information
Information on toxicological effects
: Not classified P&G Professional FAIRY Non Bio
LD50 oral calculated
Citric Acid (77-92-9)
LD50 oral rat
5400 mg/kg bodyweight //OECD 401 > 2000 mg/kg OECD 402 5400 mg/kg bodyweight P&G Professional FAIRY Non Bio
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Citric Acid (77-92-9)
ATE CLP (dermal)
2001 mg/kg bodyweight Sodium Carbonate (497-19-8)
LD50 oral rat
LD50 dermal rabbit 2800 mg/kg bodyweight ATE CLP (dermal) 2001 mg/kg bodyweight Sodium C10-13 Alkyl Benzenesulfonate (68411-30-3)
LD50 oral rat
1080 mg/kg bodyweight OECD 401 > 2000 mg/kg bodyweight OECD 402 1080 mg/kg bodyweight ATE CLP (dermal) 2001 mg/kg bodyweight Sodium Silicate (1344-09-8)
LD50 oral rat
3400 mg/kg OECD 401 LC50 inhalation rat (mg/l) 3400 mg/kg bodyweight ATE CLP (dermal) 5000 mg/kg bodyweight ATE CLP (vapours) ATE CLP (dust,mist) Sodium Carbonate Peroxide (15630-89-4)
LD50 oral rat
893 mg/kg US EPA 1984 LD50 dermal rabbit 2001 mg/kg US EPA 893 mg/kg bodyweight ATE CLP (dermal) 2001 mg/kg bodyweight C14-15 Pareth-n (68951-67-7)
LD50 oral rat
500 mg/kg bodyweight ATE CLP (dermal) 2001 mg/kg bodyweight Skin corrosion/irritation : Not classified Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Sodium C10-13 Alkyl Benzenesulfonate (68411-30-3)
NOAEL (chronic, oral, animal/male, 2 years)
350 mg/kg bodyweight NOAEL (chronic, oral, animal/female, 2 years) 350 mg/kg bodyweight Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and : Acute Toxicity: based upon available data of the substances, classification criteria are not met. Carcinogenicity: based upon available data of the substances, classification criteria are not met. Corrosivity: based upon available data of the substances, classification criteria are not met. Irritation: severly irritant to eyes. Mutagenicity: based upon available data of the substances, classification criteria are not met. Repeated Dose Toxicity: based upon available data of the substances, classification criteria are not met. Sensitization: based upon available data of the substances, classification criteria are not met. Toxicity for Reproduction: based upon available data of the substances, classification criteria are not met. Other information : Likely routes of exposure: skin and eye. Information on Effects: refer to section 4. P&G Professional FAIRY Non Bio
Safety Data Sheet
according to Regulation (EC) No. 453/2010

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general
: No known adverse effects on the functioning of water treatment plants under normal use conditions as recommended. The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. Citric Acid (77-92-9)
LC50 fishes 1
440 ml/l //OECD 203, Leuciscus idus melanotus 1535 mg/l Daphnia magna NOEC chronic algae 4425 mg/l Scenedesmus quadricauda Sodium Carbonate (497-19-8)
LC50 fishes 1
Sodium C10-13 Alkyl Benzenesulfonate (68411-30-3)
LC50 fishes 1
1.67 mg/l US EPA 850.1075; Lepomis macrochirus; 96 h 2.9 mg/l OECD 202; Daphnia magna; 48 h 127.9 mg/l 88/302/EWG; Desmodesmus subspicatus; 72 h NOEC chronic fish 0.23 mg/l Oncorhynchus mykiss; 72 d NOEC chronic crustacea 0.5 mg/l Ceriodaphnia sp.; 7 d NOEC chronic algae 2.4 mg/l 88/302/EWG; Desmodesmus subspicatus; 3 d Sodium Silicate (1344-09-8)
LC50 fishes 1
1108 mg/l OECD 203, Brachydanio rerio, 1700 mg/l Daphnia magna EC50 other aquatic organisms 1 > 348 mg/l Pseudomonas putida 207 mg/l Scenedesmus subspicatus Sodium Carbonate Peroxide (15630-89-4)
LC50 fishes 1
70.7 mg/l Pimephales promelas; 96 h 4.9 mg/l Daphnia pulex; 48 h NOEC chronic crustacea C14-15 Pareth-n (68951-67-7)
LC50 fishes 1
LC50 other aquatic organisms 1 Persistence and degradability
Citric Acid (77-92-9)
Persistence and degradability
100 % OECD 301 E Sodium C10-13 Alkyl Benzenesulfonate (68411-30-3)
Persistence and degradability
C14-15 Pareth-n (68951-67-7)
Persistence and degradability
The substance is biodegradable. Unlikely to persist.
12.3. Bioaccumulative
potential
Citric Acid (77-92-9)
Log Pow
Bioaccumulative potential Not expected to bioaccumulate due to the low log Kow (log Kow < 4). Sodium C10-13 Alkyl Benzenesulfonate (68411-30-3)
BCF fish 1
1.4 OECD 123; 23 °C; pH: 6.1 Bioaccumulative potential Not expected to bioaccumulate due to the low log Kow (log Kow < 4). Sodium Silicate (1344-09-8)
Bioaccumulative potential
P&G Professional FAIRY Non Bio
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Sodium Carbonate Peroxide (15630-89-4)
Bioaccumulative potential
C14-15 Pareth-n (68951-67-7)
Bioaccumulative potential

12.4. Mobility
Sodium C10-13 Alkyl Benzenesulfonate (68411-30-3)
Log Koc
Results of PBT and vPvB assessment
P&G Professional FAIRY Non Bio
Results of PBT assessment
No presence of PBT and vPvB ingredients Component
Tetrasodium Etidronate (3794-83-0) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII Brightener 15 (16090-02-1) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII Citric Acid (77-92-9) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII Dodecylbenzene Sulfonic Acid (85536-14-7) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII Sodium C10-13 Alkyl Benzenesulfonate This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII Sodium Silicate (1344-09-8) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII Sodium Carbonate Peroxide (15630-89-4) PBT: not relevant – no registration required Sodium Metaborate (7775-19-1) PBT: not relevant – no registration required vPvB: not relevant – no registration required Zeolite (1318-02-1) PBT: not relevant – no registration required vPvB: not relevant – no registration required TAED (10543-57-4) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII Sulfuric Acid (7664-93-9) PBT: not relevant – no registration required vPvB: not relevant – no registration required Other adverse effects
Other information : No other effects known. SECTION 13: Disposal considerations
Waste treatment methods
Regional legislation (waste) : Disposal must be done according to official regulations. Disposal recommendations : The waste codes/waste designations below are in accordance with EWC. Waste must be delivered to an approved waste disposal company. The waste is to be kept separate from other types of waste until its disposal. Do not throw waste product into the sewer. Where possible recycling is preferred to disposal or incineration. For handling waste, see measures described in section 7. Empty, uncleaned packaging need the same disposal considerations as filled packaging. EURAL Waste code product : 20 01 29* - detergents containing dangerous substances 15 01 10* - packaging containing residues of or contaminated by dangerous substances SECTION 14: Transport information
Not applicable
14.2.
UN proper shipping name
Not applicable
14.3.
Transport hazard class(es)
Not applicable
14.4. Packing
Not applicable
14.5. Environmental
P&G Professional FAIRY Non Bio
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Special precautions for user
Not applicable
14.7.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
Ingredient label : 15-30% Oxygen-based bleaching agents; 5-15% Anionic surfactants; <5% Non-ionic surfactants, Phosphonates, Polycarboxylates, Zeolites; Optical brighteners, Perfumes. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions Contains no substance on the REACH candidate list CESIO recommendations : The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. 15.1.2. National
regulations
No additional information available
15.2.
Chemical safety assessment
No chemical safety assessment has been carried out SECTION 16: Other information
Indication of changes
Indication of changes : Not applicable Abbreviations and acronyms
No additional information available
16.3.
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]
Classification according to Regulation (EC) No. 1272/2008 [CLP]
classification procedure
On basis of test data Relevant R-phrases and/or H-statements (number and full text) for mixture and substances
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Hazardous to the aquatic environment — AcuteHazard, Category 1 Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3 Serious eye damage/eye irritation, Category 1 Serious eye damage/eye irritation, Category 2 Oxidising Solids, Category 3 Skin corrosion/irritation, Category 2 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation May intensify fire; oxidiser Causes skin irritation Causes serious eye damage Causes serious eye irritation May cause respiratory irritation Very toxic to aquatic life Harmful to aquatic life with long lasting effects Irritating to eyes Irritating to respiratory system and skin Irritating to skin Risk of serious damage to eyes Very toxic to aquatic organisms Contact with combustible material may cause fire Dangerous for the environment O Oxidising Xi Irritant P&G Professional FAIRY Non Bio
Safety Data Sheet
according to Regulation (EC) No. 453/2010

16.5. Training
Normal use of this product shall imply use in accordance with the instructions on the packaging.
16.6. Further
information
Salts listed in Section 3 without a REACh Registration number are exempt, based on Annex V SDS P&G CLP This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product

Source: http://www.a1supplies.co.uk/NewSDS/SDSSTOCK/020.301.pdf